• Vijapure Y. A.

The reaction between Vanadium (V) and Butyric and Isobutyric acid hydrazide is carried out in a mixture of perchloric acid and sodium perchlorate. The reaction proceeds through formation of complex with reactant, which decomposes in subsequent steps to give product. The various thermodynamic parameters were determined by studying the reaction at five different temperatures ranging from 30 to 500C. Oxidation of hydrazides by Vanadium (V) proceeds through complex formation between hydrazide and the oxidant. Free radical formation can be confirmed by effect of acrylonitrile. The activation parameters were also determined and the mechanism is predicted.

Butyric acid hydrazide, Kinetics, Vanadium (V), Oxidation

"Kinetics and Mechanism of Micellar Catalyzed Oxidation Reactions of Aliphatic acid Hydrazides to their corresponding acids by Vanadium(V): A Mechanistic study", International Journal of Emerging Technologies and Innovative Research (www.jetir.org), ISSN:2349-5162, Vol.4, Issue 12, page no.7-14, December-2017, Available :http://www.jetir.org/papers/JETIR1712181.pdf

"Kinetics and Mechanism of Micellar Catalyzed Oxidation Reactions of Aliphatic acid Hydrazides to their corresponding acids by Vanadium(V): A Mechanistic study", International Journal of Emerging Technologies and Innovative Research (www.jetir.org | UGC and issn Approved), ISSN:2349-5162, Vol.4, Issue 12, page no. pp7-14, December-2017, Available at : http://www.jetir.org/papers/JETIR1712181.pdf