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Published in:

Volume 7 Issue 3
March-2020
eISSN: 2349-5162

Unique Identifier

JETIR2003232

Page Number

1607-1616

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Title

Oxidation of p-amino benzhydrazide to the Corresponding Acid by Thallium (III) in 1, 4-Dioxane Medium - A Kinetic and Mechanistic Approach

ISSN

2349-5162

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"Oxidation of p-amino benzhydrazide to the Corresponding Acid by Thallium (III) in 1, 4-Dioxane Medium - A Kinetic and Mechanistic Approach", International Journal of Emerging Technologies and Innovative Research (www.jetir.org), ISSN:2349-5162, Vol.7, Issue 3, page no.1607-1616, March-2020, Available :http://www.jetir.org/papers/JETIR2003232.pdf

Abstract

The reaction between Thallium (III) and p-amino benzhydrazide is carried out in a mixture of perchloric and hydrochloric acid medium. The reaction proceeds through formation of complex with reactant, which decomposes in subsequent steps to give product. Effect of acrylonitrile shows, that there is no formation of free radicals. The increase in [H+] and [Cl-] decreases the rate of the reaction. The increase in ionic strength does not affect the rate of reaction. The effect of temperature was studied at four different temperatures ranging from 150C to 300C. The activation parameters were also determined and a mechanism is predicted.

Key Words

kinetics, Thallium(III), Oxidation, p-amino benzhydrazide.

Cite This Article

"Oxidation of p-amino benzhydrazide to the Corresponding Acid by Thallium (III) in 1, 4-Dioxane Medium - A Kinetic and Mechanistic Approach", International Journal of Emerging Technologies and Innovative Research (www.jetir.org | UGC and issn Approved), ISSN:2349-5162, Vol.7, Issue 3, page no. pp1607-1616, March-2020, Available at : http://www.jetir.org/papers/JETIR2003232.pdf

Publication Details

Published Paper ID: JETIR2003232
Registration ID: 230020
Published In: Volume 7 | Issue 3 | Year March-2020
DOI (Digital Object Identifier):
Page No: 1607-1616
ISSN Number: 2349-5162

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Cite This Article

"Oxidation of p-amino benzhydrazide to the Corresponding Acid by Thallium (III) in 1, 4-Dioxane Medium - A Kinetic and Mechanistic Approach", International Journal of Emerging Technologies and Innovative Research (www.jetir.org | UGC and issn Approved), ISSN:2349-5162, Vol.7, Issue 3, page no. pp1607-1616, March-2020, Available at : http://www.jetir.org/papers/JETIR2003232.pdf




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