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Published in:

Volume 7 Issue 11
November-2020
eISSN: 2349-5162

Unique Identifier

JETIR2011068

Page Number

496-499

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Title

OXIDATION OF SOME GLYCOL BY N-BROMOSUCCINIMIDE IN PRESENCE OF IRIDIUM(III) CHLORIDE CATALYST IN ACIDIC MEDIUM- A KINETIC STUDY

ISSN

2349-5162

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"OXIDATION OF SOME GLYCOL BY N-BROMOSUCCINIMIDE IN PRESENCE OF IRIDIUM(III) CHLORIDE CATALYST IN ACIDIC MEDIUM- A KINETIC STUDY", International Journal of Emerging Technologies and Innovative Research (www.jetir.org), ISSN:2349-5162, Vol.7, Issue 11, page no.496-499, November-2020, Available :http://www.jetir.org/papers/JETIR2011068.pdf

Abstract

Investigation of various organic substrates is one of the most active areas of current research. The work reported in the present paper consist of the study of reaction between N-bromosuccinimide (NBS) as the oxidizing reagent and some Physiologically active compounds such as glycols viz. Propene glycol, Pentene glycol and heptane glycol in presence a of novel catalyst iridium(III) chloride. These reaction have been studied from the kinetic consideration to ascertain the mechanistic pathways, product have been isolated and positively identified in each case and possible stepwise mechanism has been isolated and positively identified in each case and possible stepwise mechanism has been outlined as detailed in the last point. Role of the catalyst has also been studied in detail. The work thus introduces a novel catalyst which has yet remained somewhat unexplored in the realm of kinetic studies of various organic substrates by mild organic oxidizing agents.

Key Words

N-Bromosuccinimide, Propene glycol, Pentene glycol, Heptene glycol, Iridium(III) chloride

Cite This Article

"OXIDATION OF SOME GLYCOL BY N-BROMOSUCCINIMIDE IN PRESENCE OF IRIDIUM(III) CHLORIDE CATALYST IN ACIDIC MEDIUM- A KINETIC STUDY", International Journal of Emerging Technologies and Innovative Research (www.jetir.org | UGC and issn Approved), ISSN:2349-5162, Vol.7, Issue 11, page no. pp496-499, November-2020, Available at : http://www.jetir.org/papers/JETIR2011068.pdf

Publication Details

Published Paper ID: JETIR2011068
Registration ID: 303011
Published In: Volume 7 | Issue 11 | Year November-2020
DOI (Digital Object Identifier):
Page No: 496-499
ISSN Number: 2349-5162

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Cite This Article

"OXIDATION OF SOME GLYCOL BY N-BROMOSUCCINIMIDE IN PRESENCE OF IRIDIUM(III) CHLORIDE CATALYST IN ACIDIC MEDIUM- A KINETIC STUDY", International Journal of Emerging Technologies and Innovative Research (www.jetir.org | UGC and issn Approved), ISSN:2349-5162, Vol.7, Issue 11, page no. pp496-499, November-2020, Available at : http://www.jetir.org/papers/JETIR2011068.pdf




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