UGC Approved Journal no 63975(19)

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Published in:

Volume 6 Issue 2
February-2019
eISSN: 2349-5162

UGC and ISSN approved 7.95 impact factor UGC Approved Journal no 63975

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Published Paper ID:
JETIRAB06213


Registration ID:
197694

Page Number

1148-1154

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Title

Preparation and Characterization of Betacyclodextrin doped Nanosize Poly(o-toluidine)

Abstract

Surfactant doped Poly (o-toluidine) (POT) was synthesized in an aqueous solution of o-toluidine and non-ionic surfactant of Betacyclodextrin (BCD) by chemical method by varying the o-toluidine to surfactant ratio. The role of doping on the structure and morphological changes in poly (o-toluidine) were characterized by FTIR, UV-Visible spectroscopy, cyclic voltammetric (CV), SEM, TGA, XRD, TEM and electrochemical impedance spectroscopy measurements and the results were analyzed. The resulting polymers exhibit an enhanced solubility in solvents like DMSO, DMF, acetone, acetonitrile and THF. UV-Vis spectra display the absorbance around 800 nm assigned to polaron form of POT. The FT-IR spectra reveals that the amine vibration peak at 1598 cm-1 is shifted to 1591 cm-1 and it confirms the interaction of POT with BCD. The SEM micrographs shows distinct morphological features of BCD doped POT. The incorporation of BCD in POT is confirmed by EDAX. The XRD results show the particle size of POT 1 is 30 nm and in the case of POT 5 the particle size is 73 nm. Electrochemical behavior was studied by CV and exhibits one oxidation peak (385.9 mV) and one reduction peak (-109.7 mV) for BCD doped POT. Impedance spectra display POT with maximum surfactant concentration exhibits maximum conductivity. The TGA results suggest a higher thermal stability for BCD doped POT than that for the pure POT. The nano-sized polymer was confirmed by TEM image.

Key Words

Poly (o-toluidine), Betacyclodextrin, XRD, Cyclic Voltammetry, morphology

Cite This Article

"Preparation and Characterization of Betacyclodextrin doped Nanosize Poly(o-toluidine)", International Journal of Emerging Technologies and Innovative Research (www.jetir.org), ISSN:2349-5162, Vol.6, Issue 2, page no.1148-1154, February-2019, Available :http://www.jetir.org/papers/JETIRAB06213.pdf

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2349-5162 | Impact Factor 7.95 Calculate by Google Scholar

An International Scholarly Open Access Journal, Peer-Reviewed, Refereed Journal Impact Factor 7.95 Calculate by Google Scholar and Semantic Scholar | AI-Powered Research Tool, Multidisciplinary, Monthly, Multilanguage Journal Indexing in All Major Database & Metadata, Citation Generator

Cite This Article

"Preparation and Characterization of Betacyclodextrin doped Nanosize Poly(o-toluidine)", International Journal of Emerging Technologies and Innovative Research (www.jetir.org | UGC and issn Approved), ISSN:2349-5162, Vol.6, Issue 2, page no. pp1148-1154, February-2019, Available at : http://www.jetir.org/papers/JETIRAB06213.pdf

Publication Details

Published Paper ID: JETIRAB06213
Registration ID: 197694
Published In: Volume 6 | Issue 2 | Year February-2019
DOI (Digital Object Identifier):
Page No: 1148-1154
Country: -, -, - .
Area: Engineering
ISSN Number: 2349-5162
Publisher: IJ Publication


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