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Published in:

Volume 7 Issue 3
March-2020
eISSN: 2349-5162

Unique Identifier

JETIRDN06035

Page Number

157-161

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Title

POLYMER SUPPORT CHLOROCHROMATE: A NOVEL OXIDANT, KINETIC AND SYNTHETIC ASPECTS

ISSN

2349-5162

Cite This Article

"POLYMER SUPPORT CHLOROCHROMATE: A NOVEL OXIDANT, KINETIC AND SYNTHETIC ASPECTS", International Journal of Emerging Technologies and Innovative Research (www.jetir.org), ISSN:2349-5162, Vol.7, Issue 3, page no.157-161, March-2020, Available :http://www.jetir.org/papers/JETIRDN06035.pdf

Abstract

The oxidation of 1- Phenylethanol has been studied spectrophotometrically to compare the polymer substrate supported reagent with a commercially available cross-linked polymeric reagent. The reagent supported on strong anion exchange resin was found to be more efficient in the oxidation reaction. The reagent is very easily separated from the reaction mixture and can be manually removed from the reaction mixture, which remains clear during and after the reaction. The kinetic of oxidation of 1-Phenylethanol with chromic acid supported on anion exchange resin like Tulsion T-42 [Cl-] in 1, 4-dioxane has been studied. The reaction is found to be of zero order each in concentration of alcohol and oxidant. The oxidation product have been isolated and characterized by its derivative, UV and FT-IR and C13 NMR spectral studies. The effect of substituent’s on the rate of oxidation and the activation parameters were determined with respect to slow step of mechanism.

Key Words

Polymer- supported chromic acid, Oxidation, 1-Phenylethanol, Kinetic, Mechanism, TulsionT-42 A [Cl-].

Cite This Article

"POLYMER SUPPORT CHLOROCHROMATE: A NOVEL OXIDANT, KINETIC AND SYNTHETIC ASPECTS", International Journal of Emerging Technologies and Innovative Research (www.jetir.org | UGC and issn Approved), ISSN:2349-5162, Vol.7, Issue 3, page no. pp157-161, March-2020, Available at : http://www.jetir.org/papers/JETIRDN06035.pdf

Publication Details

Published Paper ID: JETIRDN06035
Registration ID: 229506
Published In: Volume 7 | Issue 3 | Year March-2020
DOI (Digital Object Identifier):
Page No: 157-161
ISSN Number: 2349-5162

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Cite This Article

"POLYMER SUPPORT CHLOROCHROMATE: A NOVEL OXIDANT, KINETIC AND SYNTHETIC ASPECTS", International Journal of Emerging Technologies and Innovative Research (www.jetir.org | UGC and issn Approved), ISSN:2349-5162, Vol.7, Issue 3, page no. pp157-161, March-2020, Available at : http://www.jetir.org/papers/JETIRDN06035.pdf




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