UGC Approved Journal no 63975(19)

ISSN: 2349-5162 | ESTD Year : 2014
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Published in:

Volume 3 Issue 4
April-2016
eISSN: 2349-5162

UGC and ISSN approved 7.95 impact factor UGC Approved Journal no 63975

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Published Paper ID:
JETIR1701707


Registration ID:
319626

Page Number

41-51

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Title

Influence of Plasticizer on (PEO+PVP) Based Blended Solid Polymer Electrolyte Membraneces

Abstract

The influence of low molecular weight plasticizer on the properties of Na+ ion conducting PEO/PVP blended solid polymer electrolyte (SPE) membranes, 95[35PEO:35PVP:30NaF] : 5x, where x = PEG200 , PEG400 , PEG600 were reported. SPE films were prepared using solution cast technique. The solid polymer electrolyte film, (35PEO:35PVP:30NaF), also prepared and identified as the highest conducting composition at room temperature. Complexation of the prepared electrolytes was studied by X-ray diffraction (XRD) analysis. The optical behaviour of the SPE films was studied from ultraviolet-visible (UV-vis) spectroscopy, and the optical parameters viz. absorption edge, direct energy bandgap and indirect energy band gap were determined. Frequency dependent conductivity (σac) values were obtained from complex impedance (cole-cole) plots. It was observed that the magnitude of conductivity increased with the decrease of molecular weight of the plasticizer at room temperature. The charge transport mechanism in this SPE is mainly due to ions which were confirmed by the transference number experiment. Using this electrolyte, cells were fabricated and their discharge profiles were studied under constant load. Several cell parameters associated with the cells were evaluated.

Key Words

solid polymer electrolytes, XRD analysis, Optical behaviour, frequency dependent conductivity, transference numbers, discharge profiles.

Cite This Article

"Influence of Plasticizer on (PEO+PVP) Based Blended Solid Polymer Electrolyte Membraneces", International Journal of Emerging Technologies and Innovative Research (www.jetir.org), ISSN:2349-5162, Vol.3, Issue 4, page no.41-51, April-2016, Available :http://www.jetir.org/papers/JETIR1701707.pdf

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2349-5162 | Impact Factor 7.95 Calculate by Google Scholar

An International Scholarly Open Access Journal, Peer-Reviewed, Refereed Journal Impact Factor 7.95 Calculate by Google Scholar and Semantic Scholar | AI-Powered Research Tool, Multidisciplinary, Monthly, Multilanguage Journal Indexing in All Major Database & Metadata, Citation Generator

Cite This Article

"Influence of Plasticizer on (PEO+PVP) Based Blended Solid Polymer Electrolyte Membraneces", International Journal of Emerging Technologies and Innovative Research (www.jetir.org | UGC and issn Approved), ISSN:2349-5162, Vol.3, Issue 4, page no. pp41-51, April-2016, Available at : http://www.jetir.org/papers/JETIR1701707.pdf

Publication Details

Published Paper ID: JETIR1701707
Registration ID: 319626
Published In: Volume 3 | Issue 4 | Year April-2016
DOI (Digital Object Identifier):
Page No: 41-51
Country: -, -, India .
Area: Engineering
ISSN Number: 2349-5162
Publisher: IJ Publication


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