UGC Approved Journal no 63975

ISSN: 2349-5162 | ESTD Year : 2014
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Published in:

Volume 1 Issue 2
July-2014
eISSN: 2349-5162

UGC and ISSN approved 7.95 impact factor UGC Approved Journal no 63975

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Published Paper ID:
JETIR1701725


Registration ID:
320293

Page Number

176-188

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Title

Kinetics and Mechanism of Radical Copolymerization of Linalool with Methyl Methacrylate Initiated By AIBN

Abstract

Radical copolymerization methodology was explored by and making use of acyclic terpenoids namely linalool with methyl methacrylate (MMA) initiated by azobisisobutyronitrile (AIBN) in xylene at 80±1 oC for 50 minutes under inert atmosphere of N2. The reaction results in alternating copolymer as evidenced from reactivity ratios. The system follows ideal kinetics. The overall activation energy is 65.0 kJ / mol. Alfrey Price, Q - e parameters for linalool have been evaluated as 5.08 and -2.27. The copolymer has been characterized by 1H-NMR, FTIR and DSC. The Tg of the copolymer is 70 oC.

Key Words

Copolymerization, Linalool, Methyl methacrylate, Reactivity ratio.

Cite This Article

"Kinetics and Mechanism of Radical Copolymerization of Linalool with Methyl Methacrylate Initiated By AIBN", International Journal of Emerging Technologies and Innovative Research (www.jetir.org), ISSN:2349-5162, Vol.1, Issue 2, page no.176-188, July-2014, Available :http://www.jetir.org/papers/JETIR1701725.pdf

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2349-5162 | Impact Factor 7.95 Calculate by Google Scholar

An International Scholarly Open Access Journal, Peer-Reviewed, Refereed Journal Impact Factor 7.95 Calculate by Google Scholar and Semantic Scholar | AI-Powered Research Tool, Multidisciplinary, Monthly, Multilanguage Journal Indexing in All Major Database & Metadata, Citation Generator

Cite This Article

"Kinetics and Mechanism of Radical Copolymerization of Linalool with Methyl Methacrylate Initiated By AIBN", International Journal of Emerging Technologies and Innovative Research (www.jetir.org | UGC and issn Approved), ISSN:2349-5162, Vol.1, Issue 2, page no. pp176-188, July-2014, Available at : http://www.jetir.org/papers/JETIR1701725.pdf

Publication Details

Published Paper ID: JETIR1701725
Registration ID: 320293
Published In: Volume 1 | Issue 2 | Year July-2014
DOI (Digital Object Identifier):
Page No: 176-188
Country: -, -, India .
Area: Engineering
ISSN Number: 2349-5162
Publisher: IJ Publication


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