UGC Approved Journal no 63975

ISSN: 2349-5162 | ESTD Year : 2014
Call for Paper
Volume 9 | Issue 8 | August 2022

JETIREXPLORE- Search Thousands of research papers



WhatsApp Contact
Click Here

Published in:

Volume 2 Issue 1
January-2015
eISSN: 2349-5162

UGC and ISSN approved 7.95 impact factor UGC Approved Journal no 63975

7.95 impact factor calculated by Google scholar

Unique Identifier

Published Paper ID:
JETIR1701731


Registration ID:
320558

Page Number

218-242

Share This Article


Jetir RMS

Title

Measurement of Mark Houwink’s Constants, Reactivity Ratios and Kinetics in Radical Copolymerization of Linalool with Methyl Methacrylate Initiated by BPO

Abstract

Radical copolymerization methodology was explored by and making use of acyclic terpenoids namely linalool with methyl methacrylate (MMA) initiated by benzyol peroxide (BPO) in xylene at 80±1 oC for 50 minutes under inert atmosphere of N2. The reaction results in alternating copolymer as evidenced from reactivity ratios. The system follows ideal kinetics. The overall activation energy is 57.0 kJ / mol . The values of Mark-Houwink constants for present copolymer have been evaluated as  = 0.3 and K = 2.39 x 10-4 dl/g with the help of gel permeation chromatography. Alfrey Price, Q - e parameters for linalool have been evaluated as 4.59 and -2.24. The copolymer has been characterized by 1H-NMR, FTIR and GPC.

Key Words

Copolymerization, Linalool, Mark-Houwink’s constant, Methyl methacrylate, Reactivity ratio.

Cite This Article

"Measurement of Mark Houwink’s Constants, Reactivity Ratios and Kinetics in Radical Copolymerization of Linalool with Methyl Methacrylate Initiated by BPO", International Journal of Emerging Technologies and Innovative Research (www.jetir.org), ISSN:2349-5162, Vol.2, Issue 1, page no.218-242, January-2015, Available :http://www.jetir.org/papers/JETIR1701731.pdf

ISSN


2349-5162 | Impact Factor 7.95 Calculate by Google Scholar

An International Scholarly Open Access Journal, Peer-Reviewed, Refereed Journal Impact Factor 7.95 Calculate by Google Scholar and Semantic Scholar | AI-Powered Research Tool, Multidisciplinary, Monthly, Multilanguage Journal Indexing in All Major Database & Metadata, Citation Generator

Cite This Article

"Measurement of Mark Houwink’s Constants, Reactivity Ratios and Kinetics in Radical Copolymerization of Linalool with Methyl Methacrylate Initiated by BPO", International Journal of Emerging Technologies and Innovative Research (www.jetir.org | UGC and issn Approved), ISSN:2349-5162, Vol.2, Issue 1, page no. pp218-242, January-2015, Available at : http://www.jetir.org/papers/JETIR1701731.pdf

Publication Details

Published Paper ID: JETIR1701731
Registration ID: 320558
Published In: Volume 2 | Issue 1 | Year January-2015
DOI (Digital Object Identifier):
Page No: 218-242
Country: -, -, India .
Area: Engineering
ISSN Number: 2349-5162
Publisher: IJ Publication


Preview This Article


Downlaod

Click here for Article Preview

Download PDF

Downloads

000197

Print This Page

Current Call For Paper

Jetir RMS