UGC Approved Journal no 63975(19)

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Published in:

Volume 5 Issue 1
January-2018
eISSN: 2349-5162

UGC and ISSN approved 7.95 impact factor UGC Approved Journal no 63975

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Published Paper ID:
JETIR1801316


Registration ID:
508534

Page Number

1866-1872

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Title

Electrochemical Reduction Of Cd(III) With Itaconic Acid In Non-Aqueous Medium (60% DMF , 60% , Ethanol , 60% DMSO) : A Polarographic Approach

Abstract

The reduction of Cd(II)-Itaconic acid complexes have been investigated electrochemically in aqueous-nonaqueous medium (60% DMF, 60% Ethanol and 60% DMSO) at varying temperatures 298K and 308K. The reduction of Cd(II) was found to be reversible in nonaqueous medium for itaconic acid ligand and the formation of complexes 1:1, 1:2 and 1:3 have been reported. DeFord and Hume's method as modified by Irving has been applied for the determination of composition and stability constant of the complexes species. The mathematical Mihailov's method has been also applied for comparison the stability constant values. The changes in the thermodynamic parameters Ho, Go and So accompanying complexation have been evaluated.

Key Words

Cd(II), Itaconic acid, stability constant, reversible, thermodynamic parameters

Cite This Article

"Electrochemical Reduction Of Cd(III) With Itaconic Acid In Non-Aqueous Medium (60% DMF , 60% , Ethanol , 60% DMSO) : A Polarographic Approach", International Journal of Emerging Technologies and Innovative Research (www.jetir.org), ISSN:2349-5162, Vol.5, Issue 1, page no.1866-1872, January-2018, Available :http://www.jetir.org/papers/JETIR1801316.pdf

ISSN


2349-5162 | Impact Factor 7.95 Calculate by Google Scholar

An International Scholarly Open Access Journal, Peer-Reviewed, Refereed Journal Impact Factor 7.95 Calculate by Google Scholar and Semantic Scholar | AI-Powered Research Tool, Multidisciplinary, Monthly, Multilanguage Journal Indexing in All Major Database & Metadata, Citation Generator

Cite This Article

"Electrochemical Reduction Of Cd(III) With Itaconic Acid In Non-Aqueous Medium (60% DMF , 60% , Ethanol , 60% DMSO) : A Polarographic Approach", International Journal of Emerging Technologies and Innovative Research (www.jetir.org | UGC and issn Approved), ISSN:2349-5162, Vol.5, Issue 1, page no. pp1866-1872, January-2018, Available at : http://www.jetir.org/papers/JETIR1801316.pdf

Publication Details

Published Paper ID: JETIR1801316
Registration ID: 508534
Published In: Volume 5 | Issue 1 | Year January-2018
DOI (Digital Object Identifier):
Page No: 1866-1872
Country: Jaipur, Rajasthan, India .
Area: Chemistry
ISSN Number: 2349-5162
Publisher: IJ Publication


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