• SANDEEP V. KHANSOLE

ABSTRACT: Kinetics of oxidation of benzaldehydes by isoquinolinium bromochromate (IQBC) has been studied in aqueous acetic acid medium. The oxidation of benzaldehydes leads to the formation of corresponding carboxalic acids. The reaction is first order with respect to both benzaldehydes and IQBC and is catalyzed by hydrogen ion. Various thermodynamic parameters were calculated and discussed along with validity of isokinetic relationship. The rate of oxidation increases in a medium of low dielectric constant. The effect of substituent on rate of oxidation of benzaldehyde also studied

Kinetics, oxidation, benzaldehydes, isoquinolinium bromochromate, isokinetic relationship

"Studies on Kinetics of Oxidation of Some Benzaldehydes by Isoquinolinium Bromochromate in Aqueous Acetic Acid", International Journal of Emerging Technologies and Innovative Research (www.jetir.org), ISSN:2349-5162, Vol.5, Issue 9, page no.1101-1105, September-2018, Available :http://www.jetir.org/papers/JETIR1809296.pdf

"Studies on Kinetics of Oxidation of Some Benzaldehydes by Isoquinolinium Bromochromate in Aqueous Acetic Acid", International Journal of Emerging Technologies and Innovative Research (www.jetir.org | UGC and issn Approved), ISSN:2349-5162, Vol.5, Issue 9, page no. pp1101-1105, September-2018, Available at : http://www.jetir.org/papers/JETIR1809296.pdf