• R Betsy Clarebel
• M Amaladasan

Abstract : The cobalt µ-peroxo complex viz bis-(ethylenediamine)bis-(diethylenetriamine)µ-peroxodicobalt(III)perchlorate had been prepared by appropriate method and characterization of the prepared complex was done by FTIR and electronic spectroscopy. Potentiometric method had been employed to determine the rate of the reaction. First order kinetics was observed with respect to the effect of complex and the effect of acid concentration. The order with respect to the substrate concentration was found to be zero. The effect of added salt concentration was found to be negligible. Arrhenius and thermodynamic parameters had been calculated from the effect of temperature on the reaction rate. A probable mechanism had been proposed based on the experimental results which considered this kinetic approach as a biomimic of a model system.

Keywords : cobalt µ-peroxo complex, oxidation, kinetics, L-Asparagine , mechanism.

"A Biomimic Oxidation Behaviour of Cobalt µ-Peroxo Complex on L-Asparagine -A Kinetical Approach", International Journal of Emerging Technologies and Innovative Research (www.jetir.org), ISSN:2349-5162, Vol.5, Issue 9, page no.370-373, September-2018, Available :http://www.jetir.org/papers/JETIR1809561.pdf

"A Biomimic Oxidation Behaviour of Cobalt µ-Peroxo Complex on L-Asparagine -A Kinetical Approach", International Journal of Emerging Technologies and Innovative Research (www.jetir.org | UGC and issn Approved), ISSN:2349-5162, Vol.5, Issue 9, page no. pp370-373, September-2018, Available at : http://www.jetir.org/papers/JETIR1809561.pdf