• S.Srinivasan
• A.Elavarasan

ABSTRCT The planar Copper(II) Complex [Cu(dpdtc)2] (where dpdtc=dipropyldithiocarbamate) have been prepared, characterized by elemental analysis , electronic, infrared, NMR(‘H, 13C) spectra. Electronic spectra of complex showed bands at 435nm (λmax 20833cm-1 ε 1125 l mol-1cm-1) and 612nm (λmax 15898cm-1 ε 375 l mol-1cm-1) corresponding to dz2→ d x2-y2 and dxy→ d x2-y2 respectively. The characteristic thiouride band appeared at 1500 cm-1 for the complex . In 1H , 13 C NMR, the chemical shift of the compound appeared as a broad signal indicated the compound in paramagnetic. In In cyclic voltametry neutral copper(II)dithiocarbomate complex displayed quasi- reversible one electron reduction process assigned to be Cu(II)→← Cu(I). Themogravimetric study of the copper(II) complex clearly supported the proposed formulae of the compound. Solvothermal decomposition of the copper(II) complex was carried out for the synthesis of nanoparticals. Information on the size and morphology of the product have been confirmed on the basis of SEM and EDX analysis.

EDX, SEM,AND Dithiocarbamates,thiouride

"SYNTHESIS,SPECTRAL CHARACTERIZATION AND SOLVOTHERMAL DECOMPOSITION,OF BIS(N,NDIPROPYLDITHIOCARBAMATO) copper (II)", International Journal of Emerging Technologies and Innovative Research (www.jetir.org), ISSN:2349-5162, Vol.5, Issue 12, page no.590-600, December-2018, Available :http://www.jetir.org/papers/JETIR1812777.pdf

"SYNTHESIS,SPECTRAL CHARACTERIZATION AND SOLVOTHERMAL DECOMPOSITION,OF BIS(N,NDIPROPYLDITHIOCARBAMATO) copper (II)", International Journal of Emerging Technologies and Innovative Research (www.jetir.org | UGC and issn Approved), ISSN:2349-5162, Vol.5, Issue 12, page no. pp590-600, December-2018, Available at : http://www.jetir.org/papers/JETIR1812777.pdf