• sushma
• Geetha D. V.
• Ananda. S
• Sridhar M. A
• Lokanath N. K.

Substituted 1,3,4-thiadiazoles named 5-Propylsulfanyl-1,3,4-thiadiazol-2-ylamine, have been synthesized , crystallized by solvothermal technique using autoclave and characterized by single crystal XRD, FT-IR, UV, elemental analysis, mass and 1H-NMR spectroscopy. The liquid crystalline phase studied using POM and to understand the intermolecular interactions and crystalline phase, Hirshfeld surface analysis was carried out. The compound has been crystallized in the triclinic crystal system in the P1 ¯ space group. The geometrical parameters are a = 5.621(9) Å, b = 8.867(13) Å, c = 8.927(14) Å, α = 96.559 (14)°, β = 104.523(19)° , γ = 101.56(1)°, and Z =2. In the crystal structure cg-cg interactions are observed. Supramolecular architecture involves R_2^2(8) graph-set motif.

liquid crystal, Hirshfeld, single crystal XRD

"Studies on the synthesis, structural characterization, Hirshfeld analysis and liquid crystal study of 5-Propylsulfanyl-1,3,4-thiadiazol-2-ylamine", International Journal of Emerging Technologies and Innovative Research (www.jetir.org), ISSN:2349-5162, Vol.6, Issue 1, page no.485-494, January-2019, Available :http://www.jetir.org/papers/JETIR1901161.pdf

"Studies on the synthesis, structural characterization, Hirshfeld analysis and liquid crystal study of 5-Propylsulfanyl-1,3,4-thiadiazol-2-ylamine", International Journal of Emerging Technologies and Innovative Research (www.jetir.org | UGC and issn Approved), ISSN:2349-5162, Vol.6, Issue 1, page no. pp485-494, January-2019, Available at : http://www.jetir.org/papers/JETIR1901161.pdf