• Mamta Gupta
• Rajpal Tyagi
• Deepshikha
• Mayank

Cytochrome P450 catalyzes the oxygenation reactions (introduction of an oxygen atom into a substrate) in living organisms. Biomimetic models of cytochrome P450 such as metalloporphyrins are catalysts with high potential. In order to understand the mechanism of N-oxide formation and C-hydroxylation of nitrogen heterocycles, the oxidation of different methyl-substituted pyridines with hydrogen peroxide catalyzed by 5,10,15,20-tetraaryl manganese (III) porphyrins has been undertaken in the present work. Different substituted 5,10,15,20-tetraaryl porphyrinato manganese (III) chloride, pyridine N-oxide, 4-picoline-1oxide, 3-picoline-1-oxide, and 2-picoline-1-oxide have been prepared and characterized by UV-visible, IR, 1H NMR, and Mass spectra. HPLC analysis is also carried out.

BIOMIMETIC OXIDATION OF PICOLINES AND RELATED COMPOUNDS WITH H2O2 CATALYZED BY MANGANESE (III) 5,10,15,20-TETRAARYL PORPHYRINS

"BIOMIMETIC OXIDATION OF PICOLINES AND RELATED COMPOUNDS WITH H2O2 CATALYZED BY MANGANESE (III) 5,10,15,20-TETRAARYL PORPHYRINS ", International Journal of Emerging Technologies and Innovative Research (www.jetir.org), ISSN:2349-5162, Vol.8, Issue 11, page no.d19-d27, November-2021, Available :http://www.jetir.org/papers/JETIR2111303.pdf

"BIOMIMETIC OXIDATION OF PICOLINES AND RELATED COMPOUNDS WITH H2O2 CATALYZED BY MANGANESE (III) 5,10,15,20-TETRAARYL PORPHYRINS ", International Journal of Emerging Technologies and Innovative Research (www.jetir.org | UGC and issn Approved), ISSN:2349-5162, Vol.8, Issue 11, page no. ppd19-d27, November-2021, Available at : http://www.jetir.org/papers/JETIR2111303.pdf