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Published in:

Volume 8 Issue 12
December-2021
eISSN: 2349-5162

UGC and ISSN approved 7.95 impact factor UGC Approved Journal no 63975

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Published Paper ID:
JETIR2112112


Registration ID:
317570

Page Number

b88-b97

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Title

OXIDATION STUDY OF PIPERAZINE BY N-CHLORO-P-TOLUENESULPHONAMIDE [CAT] IN ACIDIC BUFFER MEDIUM: KINETIC AND MECHANISTIC ASPECT

Abstract

Abstract: Kinetics of oxidation of Piperazine by Chloramine-T (CAT) in buffer medium (pH 4.0) have been studied at 303K. Oxidation reaction follows first order kinetics with [CAT], [Piperazine] and inverse fractional order dependence on [H+]. Addition of halide ions, toluenesulphonamide had no effect on the rate of the reaction indicating that non-ionic species are involved in the rate limiting step. Kinetic parameters were evaluated by studying the reaction at different temperature, oxidation products were identified. A common mechanism consistent with the kinetic data has been proposed. The protonation constant of substrate has been evaluated.

Key Words

Keywords: Piperazine, Chloramine-T, Kinetics, Reaction mechanism, Oxidation

Cite This Article

"OXIDATION STUDY OF PIPERAZINE BY N-CHLORO-P-TOLUENESULPHONAMIDE [CAT] IN ACIDIC BUFFER MEDIUM: KINETIC AND MECHANISTIC ASPECT", International Journal of Emerging Technologies and Innovative Research (www.jetir.org), ISSN:2349-5162, Vol.8, Issue 12, page no.b88-b97, December-2021, Available :http://www.jetir.org/papers/JETIR2112112.pdf

ISSN


2349-5162 | Impact Factor 7.95 Calculate by Google Scholar

An International Scholarly Open Access Journal, Peer-Reviewed, Refereed Journal Impact Factor 7.95 Calculate by Google Scholar and Semantic Scholar | AI-Powered Research Tool, Multidisciplinary, Monthly, Multilanguage Journal Indexing in All Major Database & Metadata, Citation Generator

Cite This Article

"OXIDATION STUDY OF PIPERAZINE BY N-CHLORO-P-TOLUENESULPHONAMIDE [CAT] IN ACIDIC BUFFER MEDIUM: KINETIC AND MECHANISTIC ASPECT", International Journal of Emerging Technologies and Innovative Research (www.jetir.org | UGC and issn Approved), ISSN:2349-5162, Vol.8, Issue 12, page no. ppb88-b97, December-2021, Available at : http://www.jetir.org/papers/JETIR2112112.pdf

Publication Details

Published Paper ID: JETIR2112112
Registration ID: 317570
Published In: Volume 8 | Issue 12 | Year December-2021
DOI (Digital Object Identifier):
Page No: b88-b97
Country: Mandya, Karnataka, India .
Area: Chemistry
ISSN Number: 2349-5162
Publisher: IJ Publication


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