UGC Approved Journal no 63975(19)

ISSN: 2349-5162 | ESTD Year : 2014
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Published in:

Volume 9 Issue 7
July-2022
eISSN: 2349-5162

UGC and ISSN approved 7.95 impact factor UGC Approved Journal no 63975

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Published Paper ID:
JETIR2207196


Registration ID:
405687

Page Number

b784-b791

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Title

Biphasic Inspired Electrocatalytic Oxidation of Substituted Alcohols to Aldehydes or Ketones with Platinum Electrode Using Potassium Iodate as a Mediator

Abstract

Electrochemical oxidation of substituted benzyl alcohols including primary and secondary alcohols was performed in an undivided cell equipped with platinum electrodes in a biphasic medium using a potassium iodate as a mediator with con. sulphuric acid. The various substituted alcohols were efficiently oxidized to aldehydes and ketones in good yields with maximum selectivity (> 99%). The iodate-containing mediator showed a 98% yield of benzaldehyde under biphasic electrolysis. HPLC data analysis confirms the existence of a high-quality yield. The plausible carbon-centered free radical mechanism for the iodate oxidation system is explained.

Key Words

electrochemical oxidation; biphasic medium; undivided cell; free radical; substituted alcohols.

Cite This Article

"Biphasic Inspired Electrocatalytic Oxidation of Substituted Alcohols to Aldehydes or Ketones with Platinum Electrode Using Potassium Iodate as a Mediator", International Journal of Emerging Technologies and Innovative Research (www.jetir.org), ISSN:2349-5162, Vol.9, Issue 7, page no.b784-b791, July-2022, Available :http://www.jetir.org/papers/JETIR2207196.pdf

ISSN


2349-5162 | Impact Factor 7.95 Calculate by Google Scholar

An International Scholarly Open Access Journal, Peer-Reviewed, Refereed Journal Impact Factor 7.95 Calculate by Google Scholar and Semantic Scholar | AI-Powered Research Tool, Multidisciplinary, Monthly, Multilanguage Journal Indexing in All Major Database & Metadata, Citation Generator

Cite This Article

"Biphasic Inspired Electrocatalytic Oxidation of Substituted Alcohols to Aldehydes or Ketones with Platinum Electrode Using Potassium Iodate as a Mediator", International Journal of Emerging Technologies and Innovative Research (www.jetir.org | UGC and issn Approved), ISSN:2349-5162, Vol.9, Issue 7, page no. ppb784-b791, July-2022, Available at : http://www.jetir.org/papers/JETIR2207196.pdf

Publication Details

Published Paper ID: JETIR2207196
Registration ID: 405687
Published In: Volume 9 | Issue 7 | Year July-2022
DOI (Digital Object Identifier): http://doi.one/10.1729/Journal.31074
Page No: b784-b791
Country: TRICHY 2, TAMILNADU, India .
Area: Chemistry
ISSN Number: 2349-5162
Publisher: IJ Publication


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