• Prerana Bairagi
• Kirti Motwani
• B.K. Dangarh
• Monika Jangid

Kinetic reaction of oxidative conversion of benzaldehyde by pyridinium chlorochromate (PCC) have been accomplished in acetic acid and water (50 %) solvent medium in the presence of HClO4at 308K temperature. This reaction kinetics for oxidation shows first order dependence with respect to substrate and hydrogen ion [H+].As the dielectric constant of solvent increases the rate of oxidation shows a corresponding decrease.All experiments were carried out at 360nm optical density. Activation parameter have been estimated. A mechanism was proposed by observing experiments.

Benzaldehyde, PCC, oxidation etc.

"Kinetic and Mechanistic Study of Oxidative Transformation of Benzaldehyde by Pyridinium-Chlorochromate in Acetic acid-Water Medium", International Journal of Emerging Technologies and Innovative Research (www.jetir.org), ISSN:2349-5162, Vol.9, Issue 8, page no.c940-c946, August-2022, Available :http://www.jetir.org/papers/JETIR2208300.pdf

"Kinetic and Mechanistic Study of Oxidative Transformation of Benzaldehyde by Pyridinium-Chlorochromate in Acetic acid-Water Medium", International Journal of Emerging Technologies and Innovative Research (www.jetir.org | UGC and issn Approved), ISSN:2349-5162, Vol.9, Issue 8, page no. ppc940-c946, August-2022, Available at : http://www.jetir.org/papers/JETIR2208300.pdf