• Arun Kumar Saket
• K. N. Sharma

This article describes the micellar (cationic cetyltrimethylammonium bromide) catalysed oxidation of 1,5-pentane diol by piperidinium chlorochromate in aqueous acetic acid medium. The reaction proceeds via a mechanism involving fission of α-C-H bond at transition state of complex (1:1) to afford hydroxycarbonyl compound. The degree of dissociation of micellar (CTAB) complex formed with diol, þipcc and [H+] of the order of 1 to 0 was reported. The proton abstraction based mechanism in the oxidation process was verified by rate law and other kinetic parameters.

Micellar, 1,5-pentane diol, þiperidinium chlorochromate, catalysis, oxidation.

"Study on Catalysed Oxidation of 1,5-þentane diol by Piperidinium Chlorochromate in Aqueous Acetic Acid Medium ", International Journal of Emerging Technologies and Innovative Research (www.jetir.org), ISSN:2349-5162, Vol.13, Issue 2, page no.b557-b561, February-2026, Available :http://www.jetir.org/papers/JETIR2602175.pdf

"Study on Catalysed Oxidation of 1,5-þentane diol by Piperidinium Chlorochromate in Aqueous Acetic Acid Medium ", International Journal of Emerging Technologies and Innovative Research (www.jetir.org | UGC and issn Approved), ISSN:2349-5162, Vol.13, Issue 2, page no. ppb557-b561, February-2026, Available at : http://www.jetir.org/papers/JETIR2602175.pdf